Champions League Predictions, Betting Tips & Odds: Back This HUGE 551/1+ ACCA

BOYLE Sports Team 01 October 2025 at 02:55pm
Champions League Ball 2526

Reigning champions Paris St Germain are among the teams in Champions League action on Wednesday, and we’ve gone for five selections from the night’s action, which would give a near 551/1 payout.

BOYLE Sports customers can always Back Yourself by adding more picks, but these are our selections.

Barcelona vs PSG

Barcelona to draw against Paris St Germain with both teams to score @15/4

Barcelona have won seven of their eight games this season, drawing the other, and returning to the city’s Olympic Stadium as they wait for the Nou Camp to finally be finished does not seem to have caused any issues for Hansi Flick’s side.

PSG have also enjoyed a fine start, winning six of seven while keeping five clean sheets and opened their Champions League defence with a 4-0 thrashing of Atalanta.

They have won 4-1 on their last two visits to Barca, while other recent meetings between the two European powerhouses have finished 3-2, 6-1 and 4-0, with home advantage often counting for little, so we’re not anticipating a drab goalless stalemate tomorrow.

15/4
● LIVE ODDS Both Teams To Score - Outcome Draw Both Teams To Score And Match Result

Leverkusen vs PSV

Bayer Leverkusen to beat PSV Eindhoven with both teams to score @21/10

Leverkusen have had a mixed start to the season and are already seven points behind Bayern Munich after just five rounds of the Bundesliga.

They also needed a late fightback to claim a 2-2 draw at FC Copenhagen in their Champions League opener, so they will know the importance of winning at home.

PSV have won five out of seven league games, losing one, but their chances of progressing in Europe suffered a major blow after losing 3-1 at home to Union Saint-Gilloise. With Napoli, Liverpool, Atletico Madrid and Bayern Munich still to come, that was a setback PSV could have done without, and we’re expecting more disappointment for the Dutch champions tomorrow.

11/5
● LIVE ODDS Bayer Leverkusen Both Teams To Score And Match Result

Borussia Dortmund vs Athletic Bilbao

Borussia Dortmund to score in both halves against Athletic Bilbao @7/4

In-form Dortmund remain unbeaten in all competitions with five wins and two draws, while they have only conceded in two of those games, although those finished 3-3 and 4-4. Karim Adeyemi has scored in all three of his appearances and is 7/1 to open the scoring tomorrow.

Athletic were joint top of La Liga after winning their opening three games, but the wheels have fallen off since then, losing four of five games and drawing the other. Their 2-0 home loss to Arsenal has left them playing catch-up in the Champions League, but it does not get any easier with a trip to 2024 finalists Dortmund.

7/4
● LIVE ODDS Borussia Dortmund To Score in Both Halves

Napoli vs Sporting

Napoli to beat Sporting Lisbon with over 2.5 goals in total @9/4

Napoli’s 2-1 defeat at 10-man AC Milan on Saturday were the first dropped points of the domestic season for the Serie A champions, but they have also been beaten in Europe, losing 2-0 at Manchester City following the early dismissal of Giovanni Di Lorenzo.

Sporting are in flying form, winning six games out of seven at the start of their own title defence while also seeing off Kairat Almaty 4-1 in Europe. However, they have been beaten in their two hardest fixtures so far - Benfica in the Portuguese Super Cup and Porto in the league - and Napoli will be another step up again.

23/10
● LIVE ODDS Napoli/Over 2.5 Match Result And Total Goals O/U 2.5

Villareal vs Juventus

Villarreal to draw with Juventus and both teams to score @16/5

Villarreal have struggled on their travels, including losing at Tottenham in Europe, but are on an eight-game winning streak at their Estadio de la Ceramica fortress, during which they have kept five clean sheets.

Juventus remain unbeaten after six games but have not really set the world alight yet, winning their first three fixtures before drawing the next three. Their opening Champions League game was a 4-4 epic at home to Dortmund, but it would be a surprise to see something similar tomorrow.

16/5
● LIVE ODDS Both Teams To Score - Outcome Draw Both Teams To Score And Match Result

Bet on Football Odds at BOYLE Sports

*Prices are subject to fluctuation

Remember, Always Gamble Responsibly

Boyle Sports Blog Responsible Gambling Message

ROOTED IN HISTORY READY FOR THE FUTURE

ROOTED IN HISTORY READY FOR THE FUTURE